GCSE Chemistry (Combined) WJEC

This subject is broken down into 86 topics in 10 modules:

  1. The Nature of Substances and Chemical Reactions 15 topics
  2. Atomic Structure and The Periodic Table 9 topics
  3. Water 10 topics
  4. The Ever-changing Earth 9 topics
  5. Rate of Chemical Change 4 topics
  6. Bonding, Structure and Properties 9 topics
  7. Acids, Bases and Salts 7 topics
  8. Metals and their Extraction 9 topics
  9. Chemical Reactions and Energy 3 topics
  10. Crude Oil, Fuels and Carbon Compounds 11 topics
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This page was last modified on 28 September 2024.

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Chemistry (Combined)

The Nature of Substances and Chemical Reactions

Elements as Substances

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Elements as Substances

Understanding Elements

  • An element is a substance that cannot be broken down into simpler substances by chemical reactions. They are made up of one type of atom only.
  • Atoms are the smallest unit of an element. They are made up of subatomic particles: protons, neutrons, and electrons.
  • Protons carry a positive charge, neutrons carry no charge (they are neutral), and electrons carry a negative charge.
  • The number of protons in an atom (the atomic number) determines the type of element it is.

Classifying Elements

  • Elements can be classified as metals, non-metals, or metalloids (also called semi-metals) based on their physical and chemical properties.
  • Metals are typically solid at room temperature (with the exception of mercury), shiny, good conductors of heat and electricity, and malleable.
  • Non-metals can be solid, liquid or gas at room temperature, they are poor conductors of heat and electricity and are not malleable.
  • Metalloids have properties intermediate between those of metals and non-metals.

The Periodic Table of Elements

  • The Periodic Table is an organised arrangement of elements in rows and columns.
  • Elements are arranged in increasing atomic number from left to right and top to bottom. This arrangement reflects the repeating pattern of chemical properties of the elements.
  • Each horizontal row is called a period and each vertical column is called a group. Elements in the same group generally have similar chemical properties.
  • The Periodic Table is divided into several blocks: the s-block, p-block, d-block, and f-block, which can further categorise elements based on the outermost electrons of their atoms.

Chemical Symbols

  • Each element has a unique chemical symbol consisting of one or two letters. The first letter is always capitalised and the second (if present) is always lowercase.
  • These symbols are a standardised shorthand way of representing elements in chemical reactions and compounds. For example, the symbol for hydrogen is H and for oxygen is O.

Chemical Reactions and Elements

  • In a chemical reaction, atoms are rearranged to form new substances. The starting substances are called reactants and the end substances are called products.
  • In all chemical reactions, the total number of each type of atom in the reactants equals the total number in the products. This principle is known as the law of conservation of mass.
  • Chemical reactions are usually accompanied by energy changes. The energy can be released (exothermic reaction) or absorbed (endothermic reaction) during the reaction process.

Course material for Chemistry (Combined), module The Nature of Substances and Chemical Reactions, topic Elements as Substances

Chemistry (Combined)

Rate of Chemical Change

Rate of Reaction

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Rate of Reaction

Understanding Rate of Reaction

  • The rate of reaction refers to the speed at which reactants are converted into products in a chemical reaction.
  • It can be expressed in terms of the change in concentration of a reactant or a product over time.
  • The faster the reactants are used up or the more rapidly products are formed, the higher the rate of reaction.

Factors Affecting Rate of Reaction

Temperature

  • Increasing the temperature increases the rate of reaction.
  • This is because as temperature rises, particles move faster and collide more frequently and more energetically, resulting in more successful reactions.

Concentration and Pressure

  • Increasing the concentration of reactants in a solution or the pressure in a gas reaction also increases the rate of reaction.
  • Higher concentrations and pressures mean more particles in the same volume, leading to a higher chance of collisions and hence a faster reaction.

Surface Area

  • Increasing the surface area of solid reactants increases the rate of reaction.
  • Smaller particles or thinner pieces have a larger surface area exposed to other reactants, resulting in more frequent collisions and a quicker rate of reaction.

Catalysts

  • Catalysts are substances that increase the rate of reaction without being used up.
  • They provide an alternative reaction pathway with a lower activation energy, enabling more particles to react at a given temperature.

Measuring the Rate of Reaction

  • The rate of reaction can be measured by observing a change in quantity of a reactant or a product over time.
  • This could be tracking a change in mass, volume of gas produced, light transmission (for colour changes), or other observable factors.
  • To calculate the rate of reaction, you divide the quantity changed by the time taken.

Effect of Rate of Reaction on Industrial Processes

  • Understanding and manipulating rates of reaction is vital for economic and safety reasons in industrial processes.
  • Faster reactions can help achieve faster production rates, but they also consume reactants more rapidly and can be more hazardous due to the heat released.
  • Therefore, appropriate conditions and catalysts are often selected to optimise the speed, cost-effectiveness and safety of industrial chemical reactions.

Course material for Chemistry (Combined), module Rate of Chemical Change, topic Rate of Reaction

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