GCSE Chemistry (Triple) AQA

This subject is broken down into 107 topics in 12 modules:

  1. Atomic Structure and the Periodic Table 13 topics
  2. Crude oil, hydrocarbons and alkanes 11 topics
  3. Isotopes 11 topics
  4. Bonding, Structure and Properties of Matter 12 topics
  5. Quantitative Chemistry 8 topics
  6. Chemical Changes 8 topics
  7. Energy Changes 6 topics
  8. The Rate and Extent of Chemical Change 6 topics
  9. Organic Chemistry 9 topics
  10. Chemical Analysis 7 topics
  11. Atmosphere Chemistry 5 topics
  12. Using Resources 11 topics
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  • 107
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  • 38,397
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This page was last modified on 28 September 2024.

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Chemistry (Triple)

Atomic Structure and the Periodic Table

Atomic Structure: Atoms

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Atomic Structure: Atoms

Understanding Atoms

  • An atom is the smallest part of an element that can exist, typically around a hundred millionth of a centimetre across.
  • Every atom is made of three fundamental particles: protons, neutrons, and electrons.
  • The nucleus at the centre of the atom contains the protons and neutrons.
  • The electrons move in energy levels around the nucleus, also known as electron shells.

Atomic Number & Mass Number

  • The atomic number (Z) of an atom is the number of protons in its nucleus. It gives the identity of the atom.
  • The mass number (A) is the total number of protons and neutrons in the nucleus.
  • An atom is neutral because it contains equal numbers of protons (positively charged) and electrons (negatively charged).

Isotopes & Ionisation

  • Isotopes are atoms of the same element with different numbers of neutrons, and hence different mass numbers.
  • Isotopes of an element have identical chemical reactions because they have the same electron arrangement.
  • Ionisation occurs when an atom gains or loses electrons, becoming an ion. Positive ions (cations) form by losing electrons, negative ions (anions) form by gaining electrons.

Atomic Model Evolution

  • The atomic model has changed as scientists have discovered new information.
  • JJ Thomson’s 'Plum Pudding' Model discovered that atoms contain electrons. However, he believed these were embedded in a sphere of positive charge.
  • Rutherford's Alpha Particle Scattering Experiment showed that most of the atom is empty space with a tiny, dense, positive nucleus.
  • Niels Bohr improved Rutherford's model by placing electrons in specific orbits, or energy levels. The modern atomic model was based on Bohr's work.

Using Mass Spectrometry

  • Mass spectrometry can be used to find relative isotopic abundance and identify elements.
  • This method supports theories about atomic structure and isotopes.
  • It helps to calculate the relative atomic mass of an element from the relative abundances of its isotopes.

Understanding Energy Levels

  • Electrons fill the energy levels in a specific order – from lower to higher.
  • Each energy level can hold only a certain number of electrons: 2 in the first level and generally 8 in the others.
  • Electron configuration (distribution of electrons in energy levels) affects the chemical properties of atoms.

Course material for Chemistry (Triple), module Atomic Structure and the Periodic Table, topic Atomic Structure: Atoms

Chemistry (Triple)

Quantitative Chemistry

Quantitative Chemistry: Percentage Yield

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Quantitative Chemistry: Percentage Yield

Defining Percentage Yield

  • Percentage yield is a measure of the efficiency of a chemical reaction.
  • It is calculated by comparing the actual yield (the amount of product collected) with the theoretical yield (the maximum amount possible, calculated based on the balanced chemical equation).
  • It is expressed as a percentage, with 100% representing a perfectly efficient reaction where no product was lost.

Calculating Percentage Yield

  • Percentage yield is calculated using the formula percentage yield = (actual yield / theoretical yield) x 100.
  • The actual yield is usually determined experimentally, from the actual amount of product obtained in the lab.
  • The theoretical yield is calculated based on the stoichiometry of the reaction, which gives the amounts of reactants needed and products formed in a perfectly balanced reaction.

Factors Affecting Percentage Yield

  • Percentage yield can be affected by several factors, including incomplete reactions, where not all reactants are converted into products.
  • Side reactions can also reduce percentage yield, as reactants could form unintended products.
  • Practical issues such as product loss during collection or purification can also reduce the actual yield.
  • Optimizing these factors can help achieve a higher percentage yield.

Applications of Percentage Yield

  • In industrial chemistry, high percentage yield is desirable to reduce waste and lower production costs.
  • Reaction conditions are often adjusted to maximize percentage yield, such as alterations in temperature, pressure, or use of catalysts.
  • The concept of percentage yield also helps in environmentally friendly practices, as a higher yield minimises waste and the release of potentially harmful by-products.

Limitations of Percentage Yield

  • Note that it is not always possible or desirable to achieve a 100% yield in a reaction. Some reactions are reversible, meaning that the products can react to form the reactants again. In these cases, a balance must be found where the yield is satisfactory.
  • Also, in some cases, achieving a high yield could require conditions that are overly harsh or dangerous, such as extremely high temperatures or pressures. Therefore, a compromise must often be struck between yield and safety or cost considerations.

Importance of Percentage Yield in Real Life

  • The concept of percentage yield is not only important in industrial applications but also in everyday life. It can help us understand phenomena such as cooking (baking yield) or gardening (crop yield).
  • A basic understanding of percentage yield can also inform decisions about the efficiency and sustainability of different products and processes, encouraging informed and responsible choices.

Course material for Chemistry (Triple), module Quantitative Chemistry, topic Quantitative Chemistry: Percentage Yield

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