Pre-U Chemistry CAIE

This subject is broken down into 49 topics in 8 modules:

  1. Fundamentals of Chemistry 12 topics
  2. Physical Chemistry and Applications in Inorganic Chemistry 10 topics
  3. Organic Chemistry 5 topics
  4. Physical Chemistry and Applications in Organic Chemistry 6 topics
  5. Materials Chemistry 4 topics
  6. Biochemistry 4 topics
  7. Chemistry of the environment 4 topics
  8. Chemistry of Energy 4 topics
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  • 49
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  • 18,589
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  • 2+
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This page was last modified on 28 September 2024.

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Chemistry

Fundamentals of Chemistry

Moles and equations

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Moles and equations

Understanding Moles and Equations

The Mole Concept

  • The mole is a unit used in chemistry to measure the amount of a substance. It is defined as the amount of any substance that contains as many particles as there are atoms in 12 grams of pure carbon-12.
  • The quantity of atoms in a mole is known as Avogadro's Number, approximately 6.022 x 10^23.
  • Use the molar mass of an element or compound to convert between the mass in grams and the amount in moles. The molar mass is the mass of one mole of a substance and is usually expressed in g/mol.

Balancing Chemical Equations

  • A chemical equation represents a chemical reaction. Reactants are on the left-hand side (LHS), products are on the right-hand side (RHS).
  • In balanced chemical equations, the number of atoms of each element should be the same on both sides of the equation.
  • Techniques like inspection, algebraic method, or oxidation number method can help to balance complex chemical equations.

Stoichiometry in Chemical Equations

  • Stoichiometry is the study of the quantitative relationships or ratios between two or more substances undergoing a physical change or chemical change.
  • The coefficients in front of compounds in a balanced equation represent the molar ratios.
  • These ratios can be used to derive the amounts in moles of a substance produced or consumed. For example, if the equation suggests 2 moles of A react with 3 moles of B, then these ratios will apply no matter how much of A and B are involved in total.

Limiting and Excess Reactants

  • The limiting reactant or limiting reagent is the substance that is completely consumed when the chemical reaction is complete. It determines the maximum amount of products that can be formed.
  • The reactant present in a quantity greater than necessary according to the stoichiometry of the reaction is called the excess reactant.
  • By identifying the limiting and excess reactants, it's possible to calculate percent yield or reaction efficiency.

Molar Concentration

  • The molar concentration or molarity of a solution is the amount of solute, in moles, dissolved in 1 litre (L) of solution. It is usually measured in moles per litre (mol/L).
  • Concentration impacts reaction rates and can also be used in stoichiometric calculations.
  • Calculations associated with molarity and dilutions using the equation C1V1 = C2V2 should be practiced.

Remember that understanding and applying these concepts is essential in both laboratory and theoretical chemistry contexts. Practice plenty of examples and problems for better grasp of concepts.

Course material for Chemistry, module Fundamentals of Chemistry, topic Moles and equations

Chemistry

Organic Chemistry

Stereoisomerism

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Stereoisomerism

Stereoisomerism

  • Stereoisomerism is a subtype of isomerism where compounds have the same structural formula but differ in the spatial arrangement of atoms.

  • Stereoisomers are categorised into two main types: geometric isomerism and optical isomerism.

Geometric Isomerism

  • Also known as cis-trans isomerism, geometric isomerism occurs due to restricted rotation around a double bond or a ring structure, leading to different spatial arrangements.

  • The two forms are: cis isomers where similar or same groups are on the same side of the double bond, and trans isomers where similar or same groups are on opposite sides of the double bond.

  • Geometric isomers have different physical properties, for instance, boiling points and melting points but have the same molecular formula.

Optical Isomerism

  • Optical isomerism occurs when an atom, usually carbon, is bonded to four different groups, forming a chiral centre.

  • The two forms of optical isomers are mirror images that can't be superimposed upon each other like left and right hands, they are known as enantiomers.

  • Optical isomers affect polarised light differently, with each isomer rotating light in opposite directions. One will rotate light in a clockwise direction (dextrorotatory), and the other in an anticlockwise direction (levorotatory).

  • Molecules without a plane of symmetry are likely to be optical isomers.

Importance of Stereoisomerism

  • The understanding of stereoisomerism is key in organic chemistry, as these molecules play important roles in biological processes.

  • These isomers have the same molecular formula but different three-dimensional configurations, leading to differences in chemical and physical properties.

  • In the pharmaceutical industry, understanding stereoisomerism is critical as one stereoisomer of a drug may be beneficial, while the other may be harmful.

  • Many naturally occurring substances, especially organic compounds, exhibit optical isomerism.

Course material for Chemistry, module Organic Chemistry, topic Stereoisomerism

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